応用化学専攻 物質化学講座
反応有機化学研究室
2009
127 Solvent extraction of perrhenate ions with podand-type nitrogen donor ligands
Takeshi Ogata, Kenji Takeshita, Kanako Tsuda, Atsunori Mori
Separation and Purification Technology, 2009, 68 (2), 288-290.
竹下先生 TPEN誘導体 レニウム抽出
126 Substituted carbazole dyes for efficient molecular photovoltaics:
long electron lifetime and high open circuit voltage performance
Nagatoshi Koumura, Zhong-Sheng Wang, Masanori Miyashita, Yu Uemura, Hiroki Sekiguchi, Yan Cui,
Atsunori Mori, Shogo Mori, Kohjiro Hara
J. Mater. Chem., 2009, 19(27), 4829-4836.
甲村，原 （産総研） 有機色素増感太陽電池
125 Syntheses and Electrochemical Properties of TEMPO Radical Substituted Silicones:
Active Material for Organic Radical Batteries
Masahiro Suguro, Atsunori Mori, Shigeyuki Iwasa, Kentaro Nakahara, Kaichiro Nakano,
Macromol. Chem. Phys. 2009, 210 (17), 1402-1407.
すぐろ シリコーン電池
124 Direct Generation of Thiol-Capped Gold Nanoparticles
with S-protected Thiol Derivatives without Deprotection
Atsushi Sugie, Takashi Somete, Masaki Matsubara, Kiyoshi Kanie,
Atsushi Muramatsu, Atsunori Mori
THPチオエーテルからの金ナノ粒子直接合成，すぎえ 東北大 蟹江，村松Ｇ 共同研究
123 Stepwise Construction of Head-to-tail-type Oligothiophenes
via Iterative Palladium-catalyzed CH Arylation and Halogen Exchange
Naoyuki Masuda, Shunsuke Tanba, Atsushi Sugie, Daiki Monguchi,
Nagatoshi Koumura, Kohjiro Hara, Atsunori Mori
Org. Lett. 2009, 11 (11), 2297-2300
増田，丹波 ＨＴオリゴチオフェン 産総研 甲村，原 共同研究
122 C-H and C-Si functionalizations of furan derivatives. Palladium-catalyzed homocoupling and arylation reactions.
Shigeru Matsuda, Masabumi Takahashi, Daiki Monguchi, Atsunori Mori
松田 フランＣＨホモカップリング，アリール化
121 Synthesis of Thiol-Capped Gold Nanoparticles with Organometallic Reagents as a New Class of Reducing Agent
Atsushi Sugie, Tomomi Hatta, Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Chem. Lett. 2009, 38 (6), 562-563
八田 Grignard 金ナノ粒子合成
119 Direct Amination of Azoles via Catalytic C−H, N−H Coupling
Daiki Monguchi, Taiki Fujiwara, Hirotoshi Furukawa, Atsunori Mori
Org. Lett., 2009, 11 (7), 1607-1610.
Selected by the Editorial Board of SYNFACTS 2009 (6), 658.
門口，藤原 ＣＨ，ＮＨ
115 Palladium-catalyzed Arylation at C-H and C-C Bonds of Masked Thiazole Derivatives
Hirotoshi Furukawa, Suguru Matsumura, Atsushi Sugie, Daiki Monguchi, Atsunori Mori
Heterocycles, 2009, 79, 303-309.
The memorial issue for Dr. John Daly.
古川 マスク化チアゾール
112 Use of NaOH as a New Activator for the Palladium-Catalyzed Direct CH Arylation of Thiazole Derivatives
Takayuki Miyaoku, Atsunori Mori
Heterocycles 2009, 77 (1), 151-155.
The special issue for Prof. Keiichiro Fukumoto on his 75th birthday.
118 Electrophilic substitution of thiophenes with arylpalladium(II) and platinum(II) complex: Mechanistic studies on palladium-catalyzed CH arylation of thiophenes
Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, Munetaka Akita, Daiki Monguchi, Atsunori Mori
Bull. Chem. Soc. Jpn, 2009, 82 (5), 555-562.
BCSJ賞（2009年5月）
杉江，白金・パラジウム フル
2008
117 Interfacial electron transfer kinetics in metal-free organic dye sensitized solar cells: Combined effects of molecular structure of dyes and electrolytes
Masanori Miyashita, Kenji Sunahara, Tomohiro Nishikawa, Yu Uemura, Nagatoshi Koumura, Kohjiro Hara
Atsunori Mori, Takao Abe, Eiji Suzuki, Shogo Mori
J. Am. Chem. Soc., 130 (52), 17874-17881 (2008).
DOI: 10.1021/ja803534u
産総研，信州大など共同研究
116 Extraction of soft metals from acidic media with nitrogen-donor ligand TPEN and its analogs
Takeshi Ogata, Kenji Takeshita, Glenn A. Fugate, Atsunori Mori
Separation Sci. Technol., 43, 2630-2640 (2008).
DOI: 10.1080/01496390802148811
東工大竹下先生 共同研究
114 Triethylsilane as a mild and efficient reducing agent for the preparation of alkanethiol-capped gold nanoparticle
Atsushi Sugie, Takashi Somete, Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Chem. Commun. (33) , 3882-3884, (2008)
DOI: 10.1039/b806251j
金ナノ粒子，杉江 共同研究 東北大多元研（蟹江准教授，村松教授）
113 Hexylthiopene-Functionalized Carbazole Dyes for Efficient Molecular Photovoltaics: Tuning of Solar-Cell Performance by Structural Modification
Zhong-Sheng Wang, Nagatoshi Koumura, Yan Cui, Masabumi Takahashi, Hiroki Sekiguchi
Atsunori Mori, Toshitaka Kubo, Akihiro Furube, Kohjiro Hara
Chem. Mater. 20（12）, 3993-4003 (2008).
関口，高橋 産総研（甲村，原） 共同研究
111 Electrophilic Substitution of Platinum(II) Complexes with Thiophene Derivatives
Atsunori Mori, Atsushi Sugie, Hirotoshi Furukawa, Yuji Suzaki, Kohtaro Osakada, and Munetaka Akita
Chem. Lett. 2008, 37 (5), 542-543
白金錯体（チオフェン反応機構） 古川，杉江
110 Effect of the use of bulky alkylphosphines in the Sonogashira Coupling with Aqueous Ammonia
Sachio Fukuoka, Tetsuro Naito, Hiroki Sekiguchi, Takashi Somete, Atsunori Mori
Heterocycles 2008, 76 (1), 819-826.
The special issue for Prof. Ryoji Noyori on his 70th birthday.
福岡
109 Controlled Homeotrophic and Homogeneous Orientations for Nanoscale PhaseSeparated Domain of Light Emitting Amphiphilic Block Copolymer Bearing a 2,5-Diarylthiazole Moiety
Atsunori Mori, Junichi Shikuma, Motoi Kinoshita, Tomiki Ikeda, Masahiro Misaki, Yasukiyo Ueda
Motonori Komura, Sadayuki Asaoka, Tomokazu Iyoda
Chem. Lett. 2008, 37 (3), 272-273.
108 Synthesis of thiophene derivatives via palladium-catalyzed coupling reactions
Nobumichi Arai, Takayuki Miyaoku, Shota Teruya, Atsunori Mori
Tetrahedron Lett., 2008, 49 (6), 1000-1003
2007
107 Silicone as an Organosilicon Reagent for the Palladium-Catalyzed Cross-Coupling Reaction
Masahiro Suguro, Yuichi Yamamura, Tooru Koike, Atsunori Mori
React. Funct. Polym., 2007, 67 (11), 1264-1276.
（鶴田禎二先生，米寿記念号）
106 Photoluminescent and Liquid-Crystalline Properties of Donor-Acceptor-Type 2,5-Diarylthiazoles (p 301-305)
Junichi Shikuma, Atsunori Mori, Kentaro Masui, Ryuichi Matsuura, Akitoshi Sekiguchi,
Haruka Ikegami, Masuki Kawamoto, Tomiki Ikeda
Chemistry - An Asian Journal, 2007, 2 (2), 301-305.
2006
105 Observation of Sequential Electrophilic Substitution of Bromothiophene and Immediate Reductive Elimination of Arylpalladium Complexes
A Sugie, K. Kobayashi, Y. Suzaki, K. Osakada, A. Mori
Chem. Lett. 2006, 35 (10), 1100-1101.
[http://www.is.csj.jp/cgi-bin/journals/pr/index.cgi?n=ca_02&id=cl/2006.1100]
104 Introduction of Ethynylene and Thienylene Spacers into 2,5-Diarylthiazole and 2,5-Diarylthiophene
K. Kobayashi, M. S. Mohamed Ahmed, A. Mori
Tetrahedron 2006, 62 (41), 9548-9553.
doi:10.1016/j.tet.2006.07.097
モハ，こばけい スペーサー
103 Palladium-catalyzed C–H Homocoupling of Bromothiophene Derivatives and Synthetic Application to Well-defined Oligothiophenes
M. Takahashi, K. Masui, H. Sekiguchi, N. Kobayashi, A. Mori, M. Funahashi, N. Tamaoki
J. Am. Chem. Soc. 2006, 128 (33), 10930-10933. (IF 7.419)
オリゴチオフェン合成 フルペーパー 高橋
102 Palladium-catalyzed intramolecular CH arylation of fime-membered nitrogen heteroaromatics
N. Arai, M. Takahashi, M. Mitani, A. Mori
Synlett. 2006 (18), 3170-3172
分子内CH結合置換反応 新井， Heck 記念号
101 Rhodium-Catalyzed Hydrosilylation of Internal Alkynes with Silane Reagents bearing Heteroatom Substituents. Studies on the Regio-/Stereochemistry and Transformation of the Produced Alkenylsilanes by Rhodium-Catalyzed Conjugate Addition
Tomoyuki Sanada, Tsuyoshi Kato, Makoto Mitani, Atsunori Mori
Adv. Synth. Cat. 348 (1-2), 51-54 (2006) (IF 4.632)
DOI: 10.1002/adsc.200505289
内部アルキンヒドロシリル化 真田，加藤
2005
100 Palladium-Catalyzed Coupling Reactions of Bromothiophenes at the C–H Bond Adjacent to the Sulfur Atom in the Presence of AgNO3/KF
K. Kobayashi, A. Sugie, M. Takahashi, K. Masui, A. Mori
Org. Lett. 2005, 7 (22), 5083-5085
ブロモチオフェンカップリング反応 こばＫ，すぎえもん
99 One-pot construction of pyrazoles and isoxazoles with palladium-catalyzed four-component coupling
M. S. Mohamed Ahmed, K. Kobayashi, A. Mori
Org. Lett. 2005, 7 (20), 4487-4489
4成分カップリング反応によるピラゾール，イソキサゾール合成 モハメド
98 New Activators for the Coupling Reaction of Terminal Alkynes with Organic Halides
M. S. Mohamed Ahmed, A. Sekiguchi, T. Shimada, J. Kawashima, A. Mori
Bull. Chem. Soc. Jpn. 2005, 78 (2), 327-330
酸化銀，ＴＢＡＯＨ アルキンカップリング反応フルペーパー モハメド
97 Aqueous Ammonia as a New Activator for Sonogashira Coupling
M. S. Mohamed Ahmed, A. Sekiguchi, K. Masui, A. Mori
Bull. Chem. Soc. Jpn. 2005, 78 (1), 160-168
アンモニア水薗頭カップリングフルペーパー モハメド
2004
96 Addition of organostannanes to isocyanate catalyzed by a rhodium complex
T. Koike, M. Takahashi, N. Arai, A. Mori
Chem. Lett. 2004, 33 (10), 1364-1365.
イソシアナートへの有機スズの付加反応，ロジウム触媒，フェノールの添加効果，小池
95 Sonogashira Coupling with Aqueous Ammonia Directed to the Synthesis of Azotolane Derivatives
M. S. Mohamed Ahmed, A. Mori
Tetrahedron 2004, 66 (44), 9977-9982
アゾベンゼン基（他プロトン性の極性官能基）をもつ基質での薗頭カップリング モハ
94 Syntheses and Properties of Donor-Acceptor-Type 2,5-Diarylthiophene and 2,5-diarylthiazole
K. Masui, A. Mori, K. Okano, K. Takamura, M. Kinoshita, T. Ikeda
Org. Lett. 2004, 6 (12), 2011-2014
増井，チオフェンとチアゾールの合成，物性 池田研との共同研究
93 Palladium-catalyzed C-H homocoupling ot thiophenes: Facile construction of bithiophene structure
K. Masui, H. Ikegami, A. Mori
J. Am. Chem. Soc., 2004, 126 (16), 5074-5075.
増井，池上 チオフェンホモカップリング
92 Stereodivergent Syntheses of (Z)- and (E)-Alkenylsilanes via Hydrosilylation of Terminal Alkynes Catalyzed by Rhodium(I) Iodide Complexes and Application to Silicon-Containing Polymer Syntheses
A. Mori, E. Takahisa, Y. Yamamura, T. Kato, A. P. Mudalige, H. Kajiro, K. Hirabayashi, Y. Nishihara, T. Hiyama
Organometallics, 2004, 23 (8), 1755-1765
ヒドロシリル化反応，高分子合成フルペーパー，高久ら
2003
91 Palladium-Catalyzed Cross-Coupling Reaction of Silicone with Aryl Chlorides
T. Koike, A. Mori Synlett., 2003, (12) 1850-1852.
小池，シリコーンカップリング（クロロアレーン）
90 Carbonylative Sonogashira Coupling with Aqueous Ammonia
M. S. Mohamed Ahmed, A. Mori Org. Lett., 2003, 5 (17), 3057-3060
Mohamed, カルボニル化カップリング
89 Facile Synthesis of 2,5-Diarylthiazoles via Palladium-Catalyzed Tandem C-H Substitutions. Design of Tunable Light Emission and Liquid Crystalline haracteristics
A. Mori, A. Sekiguchi, K. Masui, T. Shimada, M. Horie, K. Osakada, M. Kawamoto, T. Ikeda
J. Am. Chem. Soc.., 2003, 125 (7), 1700-1701
増井，関口 チアゾール
88 Iridium-catalyzed Mizoroki-Heck-type reaction of organosilicon reagents
T. Koike, X. Du, T. Sanada, Y. Danda, A. Mori, Angew. Chem., Int. Ed. 2003, 42 (1), 89-92.
小池，杜，真田 イリジウムHeck
2002
87 Disproportionation of PtPh(CH2CoMe)(cod) and Conproportionation of PtPh2(cod) and Pt(CH2COMe)2(cod) via Intermolecular Phenyl Ligand Transfer
Y. Suzaki, Y. Yamamura, A. Mori, K. Osakada*
Organometallics, 21 (24), 5254-5258
http://pubs3.acs.org/acs/journals/doilookup?in_doi=10.1021/om0204991
86 Sonogashira coupling with aqueous ammonia
A. Mori, M. S. Mohaded Ahmed, A. Sekiguchi, K. Masui, T. Koike
Chem. Lett. (7), 756-757 (2002).
モハメド，関口，増井 アンモニア薗頭
85 [Rh(OH)(cod)]2 (cod=1,5-cyclooctadiene): A highly efficient catalyst for 1,4-hydrosilylation of alfa, beta-unsaturated carbonyl compounds
A. Mori, T. Kato
Synlett (7), 1167-1169 (2002)
加藤，ロジウム触媒1，4-還元
84 Chirality transfer from silicon to carbon via diastereoselective Simmons-Smith cyclopropanation of chiral alkenylsilanols
Y. Yamamura, F. Toriyama, T. Kondo, A. Mori
Tetrahedron Asymmetry 13 (1), 13-15 (2002)
山村 鳥山, キラルシラノールの不斉転写 Simmons-Smith
83 Silicone as organosilicon reagent 2. Rhodium-catalyzed conjugate addition of the silicone reagent to a,b-unsaturated carbonyl compounds.
T. Koike, Xi. Du, A. Mori, and K. Osakada
Synlett (2), 301-303 (2002)
小池 杜 シリコーン，クロロシランの共役付加 速報
82 Rhodium-catalyzed addition of aryl- and alkenylsilanediols to aldehydes.
T. Fujii, T. Koike, A. Mori, and K. Osakada
Synlett (2), 297-300 (2002)
藤井 アルデヒドへのアリールシランジオー ル，アルケニルシランジオールの付加反応 速報
81 Rhodium-catalyzed hydroarylation and -alkenylation of alkynes with silanediols. A crucial role of the hydroxy group for the catalytic reaction
T. Fujii, T. Koike, A. Mori, and K. Osakada
Synlett (2), 295-296 (2002).
藤井 アルキンへのアリールシランジオール， アルケニルシランジオールの付加反応 速報
2001
80 Hydroxorhodium complex-catalyzed carbon-carbon bond forming reactions of silanediols with a,b-unsaturated carbonyl compounds. Mizoroki-Heck-type reaction vs conjugate addition
A. Mori, Y. Danda, T. Fujii, K. Hirabayashi, K. Osakada
J. Am. Chem. Soc. , 123 (43), 10774-10775 (2001)
段々，藤井 シランジオール Heck and 1,4 ロジウム触媒，速報
79 International chemistry olympiad: Survey on the circumstances of its participant countries.
M. M. Ito, T. Tatsumi, H. Hosoya, K. Kamogawa, A. Mori, Y. Noda, H. Sugimura, Y. Takeuchi, K. Tatsuta, Y. Ueno, T. Yamanouchi
Chem. Education, J. 5, 5-16 (2001).
化学教育（まったく無関係）
78 Mizoroki-Heck type reaction of organoboron reagents with alkenes and alkynes. A Pd(II)-catalyzed pathway with Cu(OAc)2 as an oxidant
X. Du, M. Suguro, K. Hirabayashi, A. Mori, T. Nishikata, N. Hagiwara, K. Kawata, T. Okeda, H.-F. Wang, K. Fugami, M. Kosugi
Org. Lett. 3 (21), 3313-3316 (2001)
杜，群馬大共同研究 ボロン酸Heck型反応 パラジウム触媒（酢酸銅）
77 Homo-coupling polycondensation of bis(alkynylsilane)s mediated by copper(I) chloride. A new synthesis of poly(arylene-1,3-butadiynylene)s
Y. Nishihara, T. Kato, J. Ando, A. Mori, T. Hiyama
Chem. Lett. (10), 950-951 (2001)
西原・加藤， ホモカップリング重合 銅，速報（桜井先生古希記念号）
76 Silicone as a new class of organosilicon reagent for the palladium-catalyzed cross-coupling reaction
A. Mori and M. Suguro
Synlett (6), 845-847 (2001)
須黒，シリコーン クロスカップリング 酸化銀 TBAF，速報
75 Reaction of HOSiMe2Ar with Pt-PPh3 complexes leading to Si-C bond activation or formation of a siloxoplatinum comples
N. Mintcheva, Y. Nishihara, A. Mori, K. Osakada*
J. Organomet. Chem., 629(1-2), 61-67 (2001)
Neli 西原， シラノール トランスメタル化 白金，フル（71？）
74 Isomerization of (E)-alkenylsilanes to (Z)-isomers using hydrosilanes and RhI(PPh3)3
A. Mori, E. Takahisa, Y. Nishihara, and T. Hiyama, Can.
J. Chem. 79 (11), 1522-1524 (2001)
高久， ロジウム ヒドロシリル化 異性化メカニズム，速報（Snieckus記念号）
73 A Highly Effective Pd/Cu-Catalyzed Coupling Reaction of Terminal Alkynes with Organic Halides Promoted by Tetrabutylammonium Fluoride or Hydroxide
A. Mori, T. Shimada, T. Kondo, and A. Sekiguchi
Synlett (5) , 649-651 (2001)
島田，アルキン クロスカップリング TBAF TBAOH，速報
72 Palladium-catalyzed cross-coupling polycondensation of bisalkynes with dihaloarenes activated by tetrabutylammonium hydroxide or silver(I) oxide
A. Mori, T. Kondo, T. Kato, and Y. Nishihara
Chem. Lett. (4), 286-287 (2001)
近藤， アルキン クロスカップリング重合 酸化銀 TBAOH，速報
71 Si-C bond activation of ArMe2SiOH promoted by bromoplatinum(II) complex and Ag2O. Aryl group transfer from silicon to platinum
N. Mintcheva, Y. Nishihara, M. Tanabe, K. Hirabayashi, A. Mori, K. Osakada*
Organometallics, 20 (6), 1243-1246 (2001)
Neli 西原， シラノール トランスメタル化 酸化銀 白金錯体，ノート
70 Reaction of alkynylsilanes with CuCl in polar solvents leading to alkynyl group transfer from Si to Cu
Y. Nishihara, M. Takemura, A. Mori, K. Osakada
J. Organomet. Chem., 620 (1-2), 282-286 (2001)
竹村・西原， 銅 トランスメタル化 アルキニルシラン，フル
2000
69 Non-Sonogashira-type palladium-catalyzed coupling reactions of terminal alkynes assisted by silver(I) oxide or tetrabutylammonium fluoride
A. Mori, J. Kawashima, T. Shimada, M. Suguro, K. Hirabayashi, Y. Nishihara
Org. Lett., 2 (19), 2935-2937 (2000)
川島， アセチレン カップリング 酸化銀 TBAF TBAOH 速報
68 Palladium-catalyzed cross-coupling of silanols, silanediols, and silanetriols promoted by silver(I) oxide
K. Hirabayashi, A. Mori, J. Kawashima, M. Suguro, Y. Nishihara, T. Hiyama
J. Org. Chem. 65 (17), 5342-5349 (2000)
平林， シラノール シランジオール 酸化銀 クロス， フル（60）
67 Novel Carbon-Carbon Bond Formation Through Mizoroki-Heck Type Reaction of Silanols and Organotin Compounds
K. Hirabayashi, J. Ando, J. Kawashima, Y. Nishihara, A. Mori, T. Hiyama
Bull. Chem. Soc. Jpn. 73 (6), 1409-1417 (2000)
平林， Heck シラノール スズ パラジウム／銅， フル（52 53）
66 A novel cross-coupling polycondensation of alkynylsilanes with aryl triflates catalyzed by CuCl/Pd(PPh3)4
Y. Nishihara, J. Ando, T. Kato, A. Mori, T. Hiyama
Macromolecules, 33 (8), 2779-2781 (2000)
西原・安藤， クロスカップリング重合 銅／パラジウム， 速報
65 Homo-Coupling Reactions of Alkenyl- and Arylfluorosilanes with Copper(I) Salts under Mild Conditions
Y. Nishihara, K. Ikegashira, F. Toriyama, A. Mori, T. Hiyama
Bull. Chem. Soc. Jpn. 73 (4), 985-990 (2000)
西原・池頭， ホモカップリング 銅， フル（43）
64 Coupling reactions of alkynylsilanes mediated by a Cu(I) salt: Novel syntheses of conjugate diynes and disubstituted ethynes
Y. Nishihara, K. Ikegashira, K. Hirabayashi, J. Ando, A. Mori, and T. Hiyama
J. Org. Chem., 65 (6), 1780-1787 (2000)
西原・池頭， アルキニルシラン ホモ＋クロス， フル（43 46 50）
63 Stereodivergent hydrosilylation of 1-alkynes catalyzed by RhI(PPh3)3 leading to (E)- and (Z)-alkenylsilanes and the application to polymer synthesis
A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, T. Hiyama
Polyhedron, 19 (5), 567-568 (2000)
高久， ロジウム ヒドロシリル化 反応＋重合， OMCOS
62 Substituent effect of 3,3,3-trifluoropropyl group on organic silanols. Palladium-mediated Mizoroki-Heck type and cross-coupling reactions
K. Hirabayashi, T. Kondo, F. Toriyama, Y. Nishihara, A. Mori
Bull. Chem. Soc. Jpn., 73 (3), 749-750 (2000)
平林， トリフルオロプロピル Heck クロス， ノート
61 Regio- and Stereocontrolled Hydrosilylation Polyaddition Catalyzed by RhI(PPh3)3. Syntheses of Polymers containing (E)- or (Z)-Alkenylsilane Moieties
A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, T. Hiyama
Macromolecules, 33 (4), 1115-1116 (2000)
高久， ロジウム ヒドロシリル化重合， 速報
