応用化学専攻 物質化学講座
反応有機化学研究室
171 Linear-selective Cross-coupling Polymerization of Branched Oligothiophene
by Deprotonative Metalation and Cross-coupling
Kohei Murakami, Shota Tanaka, Atsunori Mori
Polym. Chem., 2015, 6 (36), 6573-6578.
DOI: 10.1039/C5PY00945F
オリゴチオフェンデンドリマーの重合（村上）
170 Studies on Diastereoselective Functionalization, Optical Resolution,
and Racemization Behaviors of Macrocyclic Bisimidazole of Winding-vine-shaped Molecular Asymmetry
Yoichi Okayama, Kazuki, Maruhashi, Satoru Tsuji, Atsunori Mori
Bull. Chem. Soc. Jpn., 2015, 88 (9), 1331-1337.
doi:10.1246/bcsj.20150164
つる巻き状分子不斉ビスイミダゾール誘導体の分割，ラセミ化，官能基変換（岡山）
169 Preparation of Fluorescent Materials from Biomass-Derived Furfural and Natural Amino Acid Cysteine through Cross-Coupling Reactions for Extended π-Conjugation
Shota Tanaka, Kana Ashida, Go Tatsuta, Atsunori Mori
Synlett, 2015, 26 (11), 1496-1500. Supporting Info
DOI: 10.1055/s-0034-1380460 The special issue for Peter Vollhardt
168 Addition-Elimination of Aryldimethylaluminum to Vinylarenes Promoted by the Addition of Ketone
Kazuki Itami, Shota Tanaka, Kazuhiro Sunahara, Go Tatsuta, Atsunori Mori
Asian J. Org. Chem. 2015, 4 (5), 477-481.
伊丹
167 Enantioselective Synthesis of Macrocyclic Heterobiaryl Derivatives of Molecular Asymmetry by Molybdenum-Catalyzed Asymmetric Ring-Closing Metathesis
Yoichi Okayama, Satoru Tsuji, Yuka Toyomori, Atsunori Mori, Sachie Arae, Wei-Yi Wu, Tamotsu Takahashi, Masamichi Ogasawara
Angew. Chem. Int. Ed. 2015, 54 (16). 4927-4931.
DOI: 10.1002/anie.201500459R2 and 10.1002/ange.201500459R2
岡山 不斉メタセシス反応 北大 小笠原先生と共同研究
166 Ethylaluminum as Ethylene Source for the Mizoroki-Heck-type Reaction.
Rhodium-catalyzed Preparation of Stilbene Derivatives
Shota Tanaka, Kazuki Itami, Kazuhiro Sunahara, Go Tatsuta, Atsunori Mori
Chem. Commun, 2015, 51 (10), 1949-1952 . IF=6.718
DOI: 10.1039/C4CC09306B
165 Studies on the effect of N-heterocyclic carbene as a ligand for nickel(II)-catalyzed polymerization of thiophenes
Atsunori Mori, Makoto Fujio, Shunsuke Tamba
Heterocycles, 2015, 90 (1), 617-624
Dedicated to Prof. Isao Kuwajima
2014
164 Palladium-catalyzed a-Arylation of Carboxylic Acid Derivatives with Grignard Reagent
Daiki Tanaka, Shota Tanaka, Atsunori Mori
Eur. J. Org. Chem., 2014, (20), 4254-4257.
DOI: 10.1002/ejoc.201402450
163 Polythiophene Synthesis via Halogen Dance
Keisuke Shono, Yugo Sumino, Shota Tanaka, Shunsuke Tamba, Atsunori Mori
Org. Chem. Front., 2014, 1 (6), 678-682.
DOI:10.1039/C4QO00109E
Dedicated to Max Malacria (65th birthday)
162 Synthesis and properties of regioregular poly(3-substituted thiophene) bearing disiloxane moiety in the substituent. Remarkably high solubility in hexane
Atsunori Mori, Kenji Ide, Shunsuke Tamba, Satoru Tsuji, Yuka Toyomori, Takeshi Yasuda
Chem. Lett., 2014, 43 (5), 640-642
ヘキサン可溶ポリチオフェン 井手 NIMS共同研究
161 Nickel(II)-Catalyzed Cross-Coupling Polycondensation of Thiophenes via C‒S Bond Cleavage
Shunsuke Tamba, Kanta Fuji, Karin Nakamura, Atsunori Mori (IF=4.145)
Organometallics, 2014, 33 (1), 12-15.
丹波 CS結合切断ポリチオフェン合成
160 Rhodium-Catalyzed Cross Coupling of Vinylarenes with Arylaluminum Reagents Using Ketones
Shota Tanaka, Atsunori Mori
Eur. J. Org. Chem., 2014, (6), 1167-1171.
DOI: 10.1002/ejoc.201301757 IF=3.344
田中（将）ロジウムHeck反応
156 Introduction of Heteroarene Functionality on the Bipedal-thiol-capped Gold Nanoparticle by Deprotonative C-H Coupling with Palladium complex
Atsushi Sugie, Hiroki Yamauchi, Kei, Miyamura, Kenta Kumazawa, Shota Tanaka, Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Heterocycles, 2014, 88 (1), 213-221.
DOI: 10.3987/COM-13-S(S)1
Special Issue for Victor Snieckus
金ナノ粒子上でのチオフェン，チアゾールカップリング
2013
159 Murahashi Coupling Polymerization: Nickel(II)–N-Heterocyclic Carbene Complex-Catalyzed Polycondensation of Organolithium Species of (Hetero)arenes
Kanta Fuji , Shunsuke Tamba , Keisuke Shono , Atsushi Sugie , Atsunori Mori
J. Am. Chem. Soc., 2013, 135 (33), 12208-12211.
DOI: 10.1021/ja406374t
冨士 村橋カップリング重合
158 Facile Preparation of Poly(3-Substituted Thiophene) Block Copolymers by Nickel-catalyzed Deprotonative Polycondensation without External Generation of Thiophene Organometallic Species
Karin Nakamura, Shunsuke Tamba, Atsushi Sugie, Atsunori Mori
Chem. Lett., 2013, 40 (10), 1200-1202.
JStage http://dx.doi.org/10.1246/cl.130523
ポリチオフェン ブロック共重合 中村
157 Deprotonative metalation of chlorothiophene with Grignard reagent and catalytic cis-2,6-dimethylpiperidine under mild conditions.
Shunsuke Tamba, Kenji, Ide, Keisuke Shono, Atsunori Mori
Synlett, 2013, 24 (19), 1133-1136
DOI: 10.1055/s-0033-1338385
２６ジメチルピペリジン 重合，カップリング
155 Studies on the preference of multiple coupling in the introduction of thiophene ring into poly-halogenated aromatic compounds with nickel NHC catalyst
Shota Tanaka, Go Tatsuta, Atsushi Sugie, Atsunori Mori
Tetrahedron. Lett., 2013, 54 (15), 1976-1979.
デンドリマー 多重カップリングの反応性
154 Synthesis of high-molecular-weight head-to-tail-type poly(3-substituted-thiophene)s
by cross-coupling polycondensation with CpNiCl(NHC) as a catalyst
Shunsuke Tamba, Kanta Fuji, Hikaru Meguro, Shuji Okamoto, Tadashi Tendo,
Ryo Komobuchi, Atsushi Sugie, Takashi Nishino, Atsunori Mori
Chem. Lett., 2013, 40 (3), 281-283. Selected as Editor's Choice
冨士，丹波 超高分子量ポリチオフェン
153 Concise Synthesis of Well-Defined Linear and Branched Oligothiophenes
with Nickel-Catalyzed Regiocontrolled Cross Coupling of 3-Substituted Thiophenes
by Catalytically-Generated Magnesium Amide
Shota Tanaka, Daiki Tanaka, Go Tatsuta, Kohei Murakami, Shunsuke Tamba, Atsushi Sugie, Atsunori Mori
Chem. Eur. J., 2013, 19 (5), 1658-1665. IF = 5.925
田中将太 linear and branched oligothiophene
2012
152 Synthesis of thiol-capped gold nanoparticle with a flow system using organosilane as a reducing agent
Atsushi Sugie, Hansoo Song, Takafumi Horie, Naoto Omura, Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Tetrahedron. Lett., 2012, 53 (33), 4457-4459.
http://dx.doi.org/10.1016/j.tetlet.2012.06.056
Hansoo 金ナノ粒子フロー合成
151 Axially chiral macrocyclic E-alkene bearing bisazole component formed
by sequential C‒H homocoupling and ring-closing metathesis
Shotaro Nishio, Takashi Somete, Atsushi Sugie, Tohru Kobayashi, Tsuyoshi Yaita, Atsunori Mori
Org. Lett., 2012, 14 (10), 2476-2479. IF = 5.250
http://dx.doi.org/10.1021/ol300755y
西尾，染手 アゾールホモカップリング，メタセシス，分子不斉
150 C‒H Arylation of 3-Substituted Thiophene with Regioselective Deprotonation
by TMPMgCl·LiCl and Transition Metal Catalyzed Cross Coupling
Shota Tanaka, Shunsuke Tamba, Atsushi Sugie, Atsunori Mori
Heterocycles, 2012, 86 (1), 255-266.
DOI: 10.3987/COM-12-S(N)6
149 Synthesis of p-conjugated poly(thienylenearylene)s with nickel-catalyzed
C‒H functionalization polycondensation
Shunsuke Tamba, Youhei Okubo, Atsushi Sugie, Atsunori Mori
Polymer J., 2012, 44 (12), 1209-1213.
大久保 π共役系ポリマー合成
148 Copper-catalyzed oxidative C‒H, N‒H coupling of azoles and thiophenes
Shinobu Mitsuda, Taiki Fujiwara, Katsuyoshi Kimigafukuro, Daiki Monguchi, Atsunori Mori
Tetrahedron, 2012, 68 (18), 3585-3595. IF=2.983
http://dx.doi.org/10.1016/j.tet.2012.03.001
CH,NHカップリング
147 Studies on the generation of metalating species equivalent to the Knochel-Hauser base
in the nickel-catalyzed dehydrobrominative polymerization of thiophene derivatives
Shunsuke Tamba, Shinobu Mitsuda, Fujimaru Tanaka, Atsushi Sugie, Atsunori Mori
Organometallics, 2012, 31 (6), 2263-2267.
DOI: 10.1021/om201209z IF=3.888
丹波 金属種発生法
146 Quadruple Click. A Facile Pathway leading to Tetrakis(4-(1,2,3-triazolyl)methyl)-ethylenediamine as a New Class of Extracting Agent for Soft Metal Ions
Wataru Watanabe, Tetsuya Maekawa, Yuji Miyazaki, Tatsuya Kida, Kenji Takeshita, Atsunori Mori
Chem. Asian J., 2012, 7 (7), 1679-1683. IF=4.188
四重クリック ソフト金属抽出 渡部 渉
145 Generation of Metalated Thiophenes with Grignard Reagent and Catalytic Secondary Amine
for the Cross Coupling Reaction with Aryl Halides
Shota Tanaka, Daiki Tanaka, Atsushi Sugie, Atsunori Mori
Tetrahedron Lett., 2012, 53 (9), 1173-1176
田中将太，田中大貴 触媒量アミン＋ Gringnard クロスカップリング
141 Synthetic Approach to N,N,N',N'-Tetrakis[(2-Pyridylmethyl)ethylenediamine] (TPEN) Derivatives
Through Ruthenium-catalyzed-[2+2+2]Cycloaddition
Yuji Miyazaki, Fujimaru Tanaka, Kenji Takeshita, Atsunori Mori
Heterocycles, 2012, 84 (1), 527-535.
DOI: 10.3987/COM-11-S(P)16
Special issue for Professor Albert Padwa (75th birthday)
[2+2+2]cycloaddition, TPEN synthesis
2011
144 Synthesis of Well-defined Head-to-tail-type Oligothiophenes
by Regioselective Deprotonation of 3-Substituted Thio-phenes
and Nickel-catalyzed Cross Coupling Reaction
Shota Tanaka, Shunsuke Tamba, Daiki Tanaka, Atsushi Sugie, Atsunori Mori
J. Am. Chem. Soc. 2011, 133 (42), 16734-16737.
/doi/abs/10.1021/ja205953g
highlighted by Synfacts 2012, 8 (1), 0041 (Timothy M. Swager, Ggoch Ddeul Han)
DOI: 10.1055/s-0031-1289933
田中 オリゴチオフェン合成
143 Cross Coupling on Gold Nanoparticles. Effect of Reinforced Affinity of Organic Group with Bipedal Thiol
Atsushi Sugie, Kenta Kumazawa, Tomomi Hatta, Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Chem. Lett. 2011, 40 (12), 1450-1452.
金ナノ粒子表面クロスカップリング
142 C‒H Functionalization polycondensation of chlorothiophenes in the presence of nickel catalyst
with stoichiometric or catalytically-generated magnesium amide
Shunsuke Tamba, Keisuke Shono, Atsushi Sugie, Atsunori Mori
J. Am. Chem. Soc. 2011, 133 (25), 9700-9703.
http://pubs.acs.org/doi/abs/10.1021/ja2033525
クロロチオフェン重合 丹波
140 Synthesis and Properties of Seleno-analogue of MK-organic Dye for Photovoltaic Cells Prepared
by C‒H Functionalization Reactions of Selenophene Derivatives
Shunsuke Tamba, Ryosuke Fujii, Atsunori Mori, Kohjiro Hara, Nagatoshi Koumura
Chem. Lett. 2011, 40 (9) 922-924.
Special issue for the Nobel Prize to Cross Coupling
セレノフェン CHホモカップリング，アリール化 MK色素の合成と評価
藤井，丹波 共同研究 産総研 甲村，原
139 Thermo-responsive extraction of cadmium(II) ion with poly(TPEN-NIPA) gel. Effect of the chain length and branch in the spacer structure towards gel formation and the extracting behavior
Yusuke Inaba, Takayuki Tsumagari, Tatsuya Kida, Wataru Watanabe, Yasutaka Nakajima, Sachio Fukuoka,
Atsunori Mori, Tatsuro Matsumura, Yoshio Nakano, Kenji Takeshita
Polymer J. 2011, 43 (7), 630-634.
７月号ハイライト論文に採択
TPEN 長さ違いゲル，津曲
138 Nickel-catalyzed Dehydrobrominative Polycondensation for the Practical Preparation of Regioregular
Poly(3-substitutedthiophene)s
Shunsuke Tamba, Shota Tanaka, Youhei Okubo, Hikaru Meguro, Shuji Okamoto, Atsunori Mori
Chem. Lett. 2011, 40 (4), 398-399.
Selected as Editor's Choice
丹波 P3HT合成 綜研化学と共同研究
136 Temperature-dependent Change of Extraction Performance of Soft Cadmium(II) Ion with TPEN-NIPA gel. Studies on the Effect of Ethylenediamine Skeleton
Tetsuya Maekawa, Tatsuya Kida, Yuji Miyazaki, Wataru Watanabe, Yusuke Inaba, Kenji Takeshita, Atsunori Mori
Bull Chem. Soc. Jpn. 2011, 84 (1), 122-124.
前川TPEN エチレンジアミン骨格
2010
137 An Unexpected Reaction in the Copper/silver-catalyzed Oxidative Dimerization of Imidazole Derivatives
Takashi Somete, Daiki Monguchi, Yuji Miyazaki, Atsunori Mori
Memoirs of the Graduate Schools of Engineering and System Informatics Kobe University, 2010, 2, 1-4.
doi:10.5047/gseku.e.2010.001
135 Palladium-catalyzed C‒H Functionalization of Heteroarenes with Aryl Bromides and Chlorides
Shunsuke Tamba, Youhei Okubo, Shota Tanaka, Daiki Monguchi, Atsunori Mori
J. Org. Chem. 2010,75 (20), 6998-7001.
丹波，田中，大久保 tBuOLi カップリング
134 Iterative Extension of Thiophene Ring Leading to Head-to-tail-type Oligothiophenes
via Stepwise CH Arylation and Halogen Exchange Sequence
shunsuke Tanba, Atsushi Sugie, Naoyuki Masuda, Daiki Monguchi,Nagatoshi Koumura, Kohjiro Hara, Atsunori Mori
Heterocycles 2010, 82 (1), 505-529.
Special issue for Albert Echenmoser (85th birthday)
133 TPEN (N,N,N',N'-Tetrakis(2-pyridylmethyl)ethylenediamine) Derivatives bearing a Fluoroalkyl Substituent.
A Highly Effective Extraction of Soft Metal Ion Cd2+ and Minor Actinide Am3+
with Organic and Fluorous Solvents
Tatsuya Kida, Tatsuya Kida, Yusuke Inaba, Wataru Watanabe, Yasutaka Nakajima, Sachio Fukuoka, Kenji Takeshita, Atsunori Mori
Chem. Lett., 2010, 39 (7), 774-776.
132 Am/Eu Separation with a New Ligand, N,N,N',N'-tetrakis((4-butoxypyridin-2-yl)methyl)ethylenediamine (TBPEN), a Hydrophobic Derivative of TPEN
Tatsuro Matsumura, Yusuke Inaba, Atsunori Mori, Kenji Takeshita
J. Nuclear Sci. and Technol., 2010, 47 (2), 123-126
疎水性ＴＰＥＮの溶媒抽出（原子力機構 松村）
131 CH functionalization of heteroaromatic compounds by transition metal catalysis
Shunsuke Tanba, Taiki Fujiwara, Daiki Monguchi, Atsunori Mori
J. Phys.: Conference Series, 232, 012010 (2010).
http://dx.doi.org/10.1088/1742-6596/232/1/012010
国際会議
130 Solvent diversity in the preparation of alkanethiol-capped gold nanoparticles.
An approach with a gold(I) thiolate complex
Atsushi Sugie, Takeshi Yamanaka, Kenta Kumazawa, Tomomi Hatta, Yasukiyo Ueda,
Kiyoshi Kanie, Atsushi Muramatsu, Atsunori Mori
Chem. Lett., 2010, 39 (4), 319-321.
129 Thermo-responsive extraction of cadmium(II) ion with TPEN-NIPA gel. Effect of the number of polymerizable double bond towards gel formation and the extracting behavior
Sachio Fukuoka, Tatsuya Kida, Yasutaka Nakajima, Takayuki Tsumagari, Wataru Watanabe, Yusuke Inaba,
Atsunori Mori, Tatsuro Matsumura, Yoshio Nakano, Kenji Takeshita
Tetrahedron, 2010, 66 (9), 1721-1727.
TEPNゲル 温度応答 福岡
128 Oxidative dimerization of azoles via copper(II)/silver(I)-catalyzed CH homocoupling
Daiki Monguchi, Akira Yamamura, Taiki Fujiwara, Takashi Somete, Atsunori Mori
Tetrahedron Lett., 2010, 51 (5), 850-852.
DOI: 10.1016/j.tetlet.2009.12.016
アゾール2位CHホモカップリング 門口，山村
120 Construction of fused thiophene ring system via intramolecular CH arylation by palladium catalysis
Atsunori Mori, Nobumichi Arai, Tomomi Hatta, Daiki Monguchi
Heterocycles, 2010, 80 (1), 103-108.
DOI: 10.3987/COM-09-S(S)10
Special issue for Professor Akira Suzuki (80th birthday)
新井，八田 分子内チオフェン 鈴木 章先生８０歳記念号
